Comparison of Calcium versus Magnesium

Calcium Chloride is overall a better choice than Magnesium for road stabilization, de-icing and dust control. The following chart compares the two with a variety of factors to show that calcium chloride outperforms magnesium on all counts. In general, calcium chloride is much safer and friendlier to the environment.

Factor

CaCl2

MgCl2

Lowest temperature that product effectively melts ice

-25°F (-32°C)

Very ineffective at this point. Practical ice melting temperature of 5°F (-15°C)

Crystallization

32% CaCl2 solution (most common in winter) does not form crystals down to -25°F (-32°C)

Effectiveness limited by presence of magnesium sulfate as an impurity which crystallizes between 0°F (-18°C) and -5°F (-21°C). Result: sludge in tanks; clogging of spray nozzles and transfer pumps.

Performance on melting ice (1)

Between 0°F (-18°C) and 30°F (-1°C), melts between 30% and 55% more ice

Poor overall performance on amount of ice melted at same temperatures

Ice penetration (2)

At 20°F (-7°C), has 22% more penetration after 10 minutes and 38% after 30 minutes than MgCl2.

At 5°F (-15°C), 58% more ice penetration than MgCl2.

Slower overall ice penetration at same temperatures

Application Rate

Two parts of CaCl2 does more work in less time than three parts MgCl2.

50% to 100% more MgCl2 is needed to remove equal amount of snow and ice

Concrete Friendliness (3)

Negligible effect on concrete

Slow deterioration of concrete

Corrosive Impact

CorGuard provides even greater protection for concrete reinforcements, bridge decks, metal rebar and metal highway components (may be 80 - 90% less corrosive than road salt)

More than 2x as corrosive to 304 stainless steel than CaCl2

10 x more corrosive to mild steel than CaCl2

Toxicity (4)

Significantly less toxicity than MgCl2 in bioassay tests on rainbow trout.

CaCl2 is a common food ingredient found in beer, cheese, canned tomatoes, olives, cherries and pickles.

Rainbow trout were 5 times more sensitive to 29% MgCl2 than to 35% CaCl2

Impact on Vegetation

Used as fertilizer on fruit trees and vegetables to provide calcium uptake.

Also used as fertilizer. More harmful. Increases chloride levels in spruce trees.

Found to be more detrimental on turf grass than other deicers except urea.

Environmental Safety

Contains 64% chloride (dry weight).

A clean, organic material that does not leave an oily or powdery residue after its use.

Contains 74% chloride (dry weight).

Less effective ice melter so must use more to achieve same degree of ice control as CaCl2

Source:

  1. SGS Testing Services
  2. Midwest Research Institute
  3. American Concrete Institute's Guide to Durable Concrete
  4. British Columbia Ministry of the Environment
  5. Iowa State University


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